$users = get-mailbox
foreach ($a in $user) {$a.emailaddresses.Add("smtp:$($a.alias)@new_domain.com")}
$users | %{Set-Mailbox $_.Identity -EmailAddresses $_.Emailaddresses}
I ran this with a -WhatIf inside the last } and it worked on my setup perfectly. Exchange 2010 SP3.
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